Iodometry, also known as iodometric titration, is a method of volumetric chemical analysis, involves indirect titration of iodine liberated by reaction with the analyte, whereas iodimetry involves direct titration using iodine as the titrant. What is the Difference Between Iodometry and Iodimetry? In Iodometry two redox reactions occur. In Iodimetry, only one redox reaction process. Iodometry and Iodimetry – Download as Word Doc .doc /.docx), PDF File .pdf), Text File .txt) or read online.
|Published (Last):||6 November 2012|
|PDF File Size:||16.80 Mb|
|ePub File Size:||20.14 Mb|
|Price:||Free* [*Free Regsitration Required]|
Difference Between Iodometry and Iodimetry
The anlyte is a reducing agent. Exactly, the four types are acid-base, complexometric, precipitation and redox. Iodimetry is less common when compared to Iodometry. The tasks that you will do involve completing the same flow-charts which I will use in the talk. As mentioned in the definition, this is a direct titration method. Sodium thiosulphate needs a neutral or weak acid environment to oxidise with tetrathionate in an alkaline solution we would get sulphate oxidation ; 3.
Oxidated sulphur dioxide appears in the form of sulphur trioxide SO 3sulphuric acid or potassium bisulphate. Introduction This lecture is an introduction to iodometric and iodimetric titrations.
This makes analysis of hexacyanoferrate III troublesome as the iodide and thiosulfate decomposes in strongly acidic medium.
And finally the titrations that interest us today are the titrations involving iodine I2. Therefore, in this case, only one redox reaction takes place unlike in the case of the Iodometric titration. This absorption will cause the solution to change its colour from light yellow to a dark blue colour when titrated with standardised thiosulfate solution.
In doing so, it becomes reduced, and is therefore the element or compund that gain electrons. Iodometry and Iodimetry As you can see from the diagram, the titrant is usually delivered from a buret. Awarded from the Generalitat de Catalunya, Slide 1: My presentations Profile Feedback Log out. The iodine released is titrated using sodium thiosulphate at a known concentration with a starch indicator blue colour.
The term iodimetry, on the other hand, refers to titration using an iodine solution and is useful for determining substances that have reducing properties. Determining the concentration of these chemicals is important because hydroperoxides have a negative effect on the acceptability of the fat matrix used, and on the food fried in it, and they also decompose easily, forming molecules which are dangerous for human health.
Difference Between Iodometry and Iodimetry
Principles of the method The total sulphur dioxide in the wine sample is determined through direct iodimetric titration using starch as the indicator. The standard solution is Iodine I2 On the other hand in iodometric titrations: The reaction between the analyte and the titrant generates a product.
Exam 2 on Wed, Nov 3. Leave a Reply Cancel reply. Introduction to iodometric and iodimetric titrations There are a lot of redox titrations classified according to the titrant used. In this case the analyte is an oxidizing agent.
Difference Between Iodometry and Iodimetry l Iodometry vs Iodimetry
For example, the reaction:. Types of Chemical Reactions. Remember that we started working with acid-base titrations, then we moved on to complexometric titrations and finally we saw precipitation titrations. Titrant KMnO4 2 Dichromatometric: In Iodometric titrations, the Iodine which has been produced as a result of a previous redox reaction is been titrated with a reducing agent such kodometry thiosulfate ions. Here, the Iodine reduces to Iodide ions while the thiosulfate ions get oxidized further.
The substance of a known concentration is called the titrant. We are going to see the differences between both of the methods, the reactions which are involved and the specific titrants for the two types of iodometfy. The basis of these two types of titrations is oxidation-reduction, and we can use it to determine redox species quantitatively.
Introduction to iodometric and iodimetric titrations Example: Iodine I2 Iodometric titrations: With red wines it is difficult to see the equivalence point because their intense red colour makes it difficult to perceive the colour change in the indicator. Some typical kinds of chemical reactions: About project SlidePlayer Terms of Service.